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The effects of the phosphorus and sulfated ash contents of engine oils on the deactivation of monolithic three-way catalysts and oxygen sensors were studied. The effect of temperature was evaluated as well. The catalysts and oxygen sensors were poisoned in a 100-hour engine bench test. As a result, it was learned that engine oils with higher phosphorus contents showed a higher concentration of phosphorus on the catalyst surfaces, and the ability of the catalysts to convert carbon monoxide and oxides of nitrogen decreased. However, the phosphorus content was not observed to have any effect on hydrocarbons. The sulfated ash reduced the phosphorus concentration on the catalyst surface, but it also had a negative effect on the catalytic activity. The deactivation of the catalysts was much more noticeable at 800°C than at 720°C. In the tests at 720°C and 800°C, no deactivation of the oxygen sensors was observed, regardless of the composition of the engine oil.

Fifty percent distillation temperature (T50) can be used as a warm-up driveability indicator for a hydrocarbon-type gasoline. MTBE-blended gasoline, however, provides poorer driveability than a hydrocarbon-type gasoline with the same T50. The purposes of this paper are to examine the reason for poor engine driveability caused by MTBE-blended gasolines, and to propose a new driveability indicator for gasolines including MTBE-blended gasolines. The static and dynamic evaporation characteristics of MTBE-blended gasolines such as the evaporation rate and the behavior of each component during evaporation were analyzed mainly by using Gas Chromatography/Mass Spectrometry. The results of the analysis show that the MTBE concentration in the vapor, evaporated at ambient temperature (e.g. 24°C), is higher than that in the original gasoline. Accordingly, the fuel vapor with enriched MTBE flows into the combustion chamber of an engine just after the throttle valve is opened.

The authors, et al. have succeeded in the practical application of the abradable flame spray coating, used in aircraft engines for the prevention of air leakage and the improvement of efficiency, to automobile turbochargers for the first time in the world. Two layers consisting of a bond coated layer and an abradable layer used to be coated by separate spray nozzles under the conventional technique. In this paper, equations of relations between various flame spray coating conditions and the quality of coated film, which were derived from measured results, will be described. Flame spray coating conditions, that allow the double layer coating by the same spray nozzle, have been determined for each layer. Temperatures and speeds of the flame were measured by means of two-color type high-speed cameras, and equations of their relations with the flame spray coating conditions are derived from the measured result.

The use of ceramic insulation to reduce engine heat loss and thus improve fuel economy was examined but found to be detrimental rather than advantageous. This paper analyzes the reasons and presents an alternative approach, namely minimizing the heat transfer area. Experiments were conducted to determine the effects of surface smoothness on BSFC, output torque, heat release rate and piston temperature. It was found that with a mirror-finished combustion chamber, heat loss is decreased and consequently engine output is raised, while fuel consumption is lowered. The percentage reduction in heat loss was ascertained by numerically simulating combustion and was confirmed by FEM analysis of piston thermal distribution.

Automotive catalysts with a good thermal durability have been developed by modifying the composition of additives. The stability of alumina supports against the loss of the surface area depends on the ionic radius and amount of additives. Some lanthanides and alkaline earthes with large ionic radii of 0.11-0. 15nm are most effective. Among these elements, lanthanum improves not only the alumina stability but the catalytic activities of rhodium and cerium oxide. Infrared spectroscopic studies show that lanthanum oxide affects NO adsorbed on Rh to improve the activity for NO reduction. Moreover, lanthanum forms the complex oxide with cerium to improve the activity of cerium oxide. CO pulse reactions on the complex oxide (Ce, La)O2 -x have proved that the oxygen defect in the lattice promotes the diffusion of oxygen atoms to improve the oxide activity.

The second generation methanol lean burn system has been developed. The power unit is a new, 4 valve 1.6L in-line four with compact combustion chambers. Lean misfire limit was extended by using a swirl control valve in the intake port which improves combustion under partial load. Lean mixture control is made by using a signal from lean mixture sensor provided in the exhaust manifold. An EGR system has been newly adopted to reduce NOx emissions and a under-floor type catalyst is also used to reduce formaldehyde emission in the cold transient mode in addition to the manifold type catalyst. Permissible excess air ratio range (PEXARR) was defined and used to indicate the potential for reducing vehicle NOx emissions in engine dynamometer tests to optimize compression ratio, valve timing and swirl ratio and to evaluate the effect of the EGR.

A two-color high speed shutter TV camera system has been developed as a new sensing device for measuring the flame temperature in engines. The TV camera system can measure the radiant intensities of high temperature substances accurately and rapidly. And, the two-dimensional temperature distribution can be easily calculated from the radiant intensities by using an image processor. This system is applicable to measurement of flame temperatures in diesel and gasoline engines. The relation between the progress of combustion phenomena and the measured temperature distribution is clearly explained. It is confirmed that the system is effective for measurement of the flame temperature distribution in engines.

Recently engine sound quality is becoming more noticeable as noise level in a vehicle passenger compartment has been decreasing. It is necessary to reduce such discomforting noise as rumbling noise in order to improve engine sound quality. This paper describes the experimental study to find out causes of rumbling noise in an engine structure and several investigations to reduce rumbling noise. Some new approaches have been introduced to evaluate the influence of an combustion impact, the movement of a crankshaft, timing of rumbling noise and so on. The result shows that the primary cause of rumbling noise is the movement of a crankshaft due to the impact of combustion and next is the vibration characteristics of the engine-transmission assembly (power plant). Finally superior engine sound quality is achieved by increasing counterweights and stiffness of a crankshaft and also by optimizing the spark advance and improving vibration characteristics of various engine parts.

Piston ring moving zone in the cylinder is one of the most critical lubrication regimes in diesel engines. This area is susceptible to combustion substances. In particular, abnormal wear is occasionally detected due to Exhaust Gas Recirculation (EGR) system equipment. In Japan, NOx emission requirements for passenger car diesels have become more stringent effective October 1, 1986. OEMs tend to apply EGR systems to reduce NOx in exhaust gas. In order to identify the phenomenon of abnormal cylinder wear of EGR equipped engine, engine bench tests were conducted under varied conditions in EGR equipment, cooling water temperature and fuel sulfur content. The test results suggest that wear caused at low temperature is mainly corrosive wear attributable to sulfuric acid formed by reaction with fuel sulfur and condensed water.

Fuel and air behavior in the induction passage of a 4-valve engine were investigated in order to improve response at low and medium engine speeds. It was found that response is affected not only by wall vetting but also by fuel being pushed back into the intake manifold and by a lack of fuel which occurs during the transient. Futhermore, fuel-air mixing was found to be insufficient at certain injection timings, resulting in poor combustion and a consequent increase in exhaust emission and fuel consumption. This paper describes the factors of the fuel injection system which are critical for optimum response. Recommendations are made for injector location and injection timing and a proposal is put forward for a system of compensatory fuel injection to improve combustion efficiency during acceleration.

One of the main causes of the inadequate transient response of a 4-valve engine was established as being partition wall-wetting. The possibility of resolving this problem by improving fuel atomization was investigated. An air-mix type injector, although producing finer droplets with more uniform distribution, was not found effective in improving transient response. The development of a two-hole injector is described. This new injector produces twin sprays which are directed into the siamese intake ports without wetting the partition wall. As a consequence, the lean A/F ratio excursion is reduced, torque stumble is eliminated and the conversion efficiency of a three-way catalyst is increased.

A methanol fueled, lean burn system has been developed to improve both specific fuel consumption and NOx emissions. A 1.6L four-cylinder engine with increased compression ratio has been used to develop this system. Three major components of the Toyota Lean Combustion System (T-LCS) have been applied: (1) A helical port with a swirl control valve (2) A lean mixture sensor (3) Timed, multi-point fuel injection. A 2250 lb. Inertia Weight test vehicle has been fitted with this engine, and fuel system materials have been modified. This methanol, lean burn system has improved the fuel economy by about 12% still satisfying the 1986 emission standards of the U.S.A. and Japan. Aldehyde emissions have also been evaluated.

The wear mechanisms of the methanol engine were studied using dynamometer tests. Formic acid from methanol combustion mixes with the lubricant oil and attacks the metal surfaces. The iso tacho prorissis method was successfully applied to analyze the formic acid content of the used oil. A large amount of condensed water is also formed by methanol combustion and accelerates the wear. Wear can be effectively reduced by shortening lubricant oil change intervals, by using a special oil and by durable surface treatment of engine parts.

The deactivation process of automotive catalysts by lead and phosphoruos were studied. The accelerated poisoning test were performed. The activity evaluation and characterisation of poisoned pellet oxidation catalysts showed the following origin of poisoning deactivations. Lead interacts with active materials and phosphorus covers over catalysts to reduce these catalytic performance. In the case of phosphorus and lead co-existence, the activity decreases rapidly because leadphosphate plugges pores of the support. In monolithic catalysts, highly axial distributions of poisons was obserbed. This characteristic distribution is advantageous for the durability of the catalyst.

Lean mixture operation and high transient response has been accomplished by the introduction of newly designed Central Injection (Ci) system. This paper describes the effects of Ci design variables on its performance. Lean mixture operation has been attained by optimizing the injection interval, injection timing and fuel spray angle in order to improve the cylinder to cylinder air-fuel ratio distribution. Both air-fuel distribution and transient engine response are affected by the fuel spray angle. Widening the fuel spray angle improves the air-fuel distribution but worsen the transient engine response. This inconsistency has been solved by off-setting the injector away from the center axis of the throttle body and optimizing the fuel spray angle.

T-LCS (TOYOTA LEAN COMBUSTION SYSTEM ) has made the engine possible to be operated with very lean mixture over 22 of air-fuel ratio, and achieved the NOx reduction and the improvement of fuel economy. This system has two features, one of which is the feed-back control of lean mixture strength using the LEAN MIXTURE SENSOR that has been newly developed. The other feature is the improved combustion through the SWIRL CONTROL VALVE and individual timing control of fuel injection for each cylinder. The influence of the test patterns, the vehicle weight and the air-fuel ratio on the exhaust emissions of lean combustion system has been examined and the results are reported in this paper.

A helical port with a swirl control valve (SCV) has been developed to satisfy two inconsistent requirements of achieving sufficient swirl generation to improve the combustion and still maintaining high volumetric efficiency. Their effects on combustion were confirmed in a single cylinder engine using high speed flame photography and cylinder pressure diagram analysis which has demonstrated faster combustion. As a result of a hot wire anemometer study, the differences in gas motion were clarified between two helical ports, one with and one without a SCV. A more active movement of the center of swirl was measured in the case of helical port with SCV which suggests the generation of higher turbulence in the cylinder.

The lean combustion system, developed for fuel economy inprovement, uses a Lean Mixture Sensor for the feedback control of air-fuel ratio in the lean mixture range. The Lean Mixture Sensor, comprises a zirconia solid electrolyte cell which has an electrochemical pumping action and a ceramic coating layer as a diffusion layer; the measurable range is from the stoichiometric to 25 of air-fuel ratio.

Periodic regeneration of the diesel particulate trap is essential to maintain the collection efficiency and exhaust gas hack pressure at acceptable levels. The objectives of this study are to describe the phenomenology of ceramic foam filter regeneration process and to present its mathematical model. Further simulation study is carried out to estimate the effects of various factors including fuel additive on the ignition and the filter bed temperature and to investigate conditions of excessive temperature which could result in filter destruction. The model is based on the assumption that the regeneration process is composed of two steps. The first step is the additional heat supply from the external energy source, and the second step is the spontaneous combustion propagation. The results from the analytical model agreed very well with the experimental results.